Identify the reagents A and B used in the following reactions :
A
Sn/HCl,Cl2/hv
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B
Cl2/hv,Zn
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C
Cl2/Fe,FeCl3
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D
Zn,Cl2/FeCl3
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Solution
The correct option is DZn,Cl2/FeCl3 The reagent A is Zn and the reagent B is Cl2/FeCl3 When phenol is heated with zinc dust, it is reduced to benzene. C6H5−OHZn−→ΔC6H6+ZnO
Benzene on chlorination with Cl2/FeCl3 gives chlorobenzene. This is an example of electrophilic aromatic substitution reaction. C6H6Cl2/FeCl3−−−−−−→C6H5−Cl