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Question

Identify the reagents A and B used in the following reactions :
475578_995c1dfc51ac42feae45b948d0cd5baf.png

A
Sn/HCl,Cl2/hv
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B
Cl2/hv,Zn
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C
Cl2/Fe,FeCl3
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D
Zn,Cl2/FeCl3
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Solution

The correct option is D Zn,Cl2/FeCl3
The reagent A is Zn and the reagent B is Cl2/FeCl3
When phenol is heated with zinc dust, it is reduced to benzene.
C6H5OHZnΔC6H6+ZnO

Benzene on chlorination with Cl2/FeCl3 gives chlorobenzene. This is an example of electrophilic aromatic substitution reaction.
C6H6Cl2/FeCl3−−−−−C6H5Cl

Option D is correct.

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