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Introduction to Optical Isomerism

Identify the ...

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Identify the type of the following reaction of carbon compounds.

$1 . {CH}_{3} - CH = CH - {CH}_{3} + {Br}_{2} \to {CH}_{3} - CHBr - CHBr - {CH}_{3} 2 . {CH}_{3} - {CH}_{3} + {Cl}_{2} \to {CH}_{3} - {CH}_{2} - Cl + HCl 3 . {CH}_{3} - {CH}_{2} - {CH}_{2} - {CH}_{2} - OH \to {CH}_{3} - {CH}_{2} - CH = {CH}_{2} + H_{2} O 4 . {CH}_{3} - {CH}_{2} - COOH + NaOH \to {CH}_{3} - {CH}_{2} - COONa + + H_{2} O 5 . {CH}_{3} - COOH + {CH}_{3} - OH \to {CH}_{3} - COO - {CH}_{3} + H_{2} O$

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Q. Identify the type of the following reaction of carbon compounds.
a. CH₃ -CH₂ -CH₂-OH → CH₃ -CH₂ -COOH
b. CH₃ -CH₂ -CH₃ → 3CO₂ + 4H₂O
c. CH₃ -CH = CH -CH₃ + Br₂ → CH₃ -CHBr - CHBr -CH₃
d. CH₃ -CH₃ + Cl₂→ CH₃ -CH₂ -Cl + HCl
e. CH₃-CH₂ -CH₂ -CH₂ -OH → CH₃ -CH₂ -CH=CH₂ + H₂O
f. CH₃-CH₂ -COOH + NaOH → CH₃ -CH₂ -COO - Na⁺ + H₂O
g. CH₃ -COOH + CH₃ -OH → CH₃ -COO- CH₃ + H₂O

Q. Examine the given structural formula and select the esters. You may also identify the chemical required for their preparation.
1.

C H_{3} - C H_{2} - C O O - C H_{3}

C H_{3} - C H_{2} - C O O H

C H_{3} - C H_{2} - C O - C H_{3}

C H_{3} - O H

C H_{3} - C H_{2} - C H_{2} O H

C H_{3} - C O O H

C H_{3} - C O O - C H_{2} - C H_{2} - C H_{3}

Q. Give the I.U.P.A.C names of the following:
CH3 - CH3
CH3 - CH2 - CH3
CH3 - CH2 - CH2 - CH3
CH3 - CH2 - CH2 - CH2 - CH3
CH2 = CH2
CH3 - CH = CH2
CH3 = CH2 - CH = CH2
CH3 - CH2 - CH2 - CH = CH2
CH =_ CH
CH3 - C =_ CH
CH3 - CH2 - C =_ CH
CH3 - CH2 - CH2 - C =_ CH
CH3 - OH
CH3 - CH2 - OH
CH3 - CH2 - CH2 - OH
CH3 - CH2 - CH2 - CH2 - OH
CH3 - CH2 - CH2 - CH2 - CH2 - OH
H - CHO
CH3 - CHO
CH3 - CH2 - CHO
CH3 - CH2 - CH2 - CHO
CH3 - CH2 - CH2 - CH2 - CHO
H - COOH
CH3 - COOH
CH3 - CH2 - COOH
CH3 - CH2 - CH2 - COOH
CH3 - CH2 - CH2 - CH2 - COOOH

Q. write IUPAC names of the following : 1. CH3 ----- CH2 ----- CH ===== CH2 2. CH3 ----- CH2 ----- CH2 ----- C ( CH3)2 ----CH3 3. CH3 ----- CH2 ----- CHO 4.CH3 ---- CH(OH) ---- CH3 5.CH3----- CH2 ----- CH2 ----- COOH

Q. find the acidic strength 1) ch3-ch2-cooh 2) cooh-ch2-cooh 3) coo^--ch2-cooh 4) ch3-ch-ch3-ch2-cooh 5) ch3-c-ch3-ch3-ch2-coo

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