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Question

Identify X, Y and Z in the given sequence of reactions.

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A
X=HBr;Y=NaNO2+HCl;Z=heat
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B
X=Br2/CCl4;Y=HNO2;Z=CH3OH
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C
X=Br2/CuBr;Y.=NaNO2+HCl;Z=NaOH
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D
X=Br2(aq.);Y=NaNO2+HCl(05OC);Z=H3PO2+H2O
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Solution

The correct option is D X=Br2(aq.);Y=NaNO2+HCl(05OC);Z=H3PO2+H2O
Reaction of aniline with bromine water at room temperature produces a white precipitate of 2,4,6 – tribromoaniline, this on reaction with nitrous acid produces diazonium salt. In aniline, the maximum electron density is found at ortho- and para-positions of the NH2 group. The NH2 group is ortho and para directing and is a powerful activating group.
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