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Question

If 0.50 L of a 0.60 M SnSO4 solution is electrolysed for a period of 30.0 min using a current of 4.60 A. If in electrodes are used, what is the final concentration of Sn2+ remaining in the solution? [at.wt. of Sn=119]

A
0.257 M
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B
0.544 M
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C
0.189 M
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D
0.514 M
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Solution

The correct option is A 0.257 M
Ans : A
Given : 0.6 mol in 1 L
then in 0.5 L = 0.3 mol of Sn2+
Mass deposited W = zit
=1192×96500×4.6×1800
= 5.1 g
Rest mass in solution = 30.6 gm
Now molority of solution = 30.6119×1
= o.257 M



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