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Question

If 104 dm3 of water is introduced into a 1.0 dm3 flask at 300 K, then how many moles of water are in the vapour phase when equilibrium is established?
(given vapour pressure of H2O at 300 K is 3170Pa;R=8.314J K1 mol1)

A
5.56×103 mol
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B
1.53×102 mol
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C
4.46×102 mol
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D
1.27×103 mol
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Solution

The correct option is D 1.27×103 mol
The volume occupied by water molecules in vapour phase is (1×104) dm3 , that is approximately (1×103)m3
pvapV=nH2Omol

3170×1×103=nH2O×8.314×300K

nH2O=3170×1×1038.314×300=1.27×103mol


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