If 10 g of Ag reacts with 1 g of sulphur, the amount of Ag2S formed will be [Atomic weight of Ag = 108 u, S = 32 u]:
Moles of Ag=massgivenmass=10108=0.093mol
Moles of S=massgivenmass=132=0.031mol
Chemical reaction involved:
2Ag+S→Ag2S
According to the reaction,
1 mole of S reacts with 2 mol of Ag.
Thus, 0.031 mol of S will react with 0.062 mol of Ag.
The given moles of Ag is 0.093 mol. This implies that Ag is present in excess, and S is the limiting reagent.
Thus, S will control the amount of Ag2S formed.
Calculating the amount of Ag2S formed:
According to the reaction,
1 mol of S produce 1 mol of Ag2S.
Thus, 0.031 mol of S will produce 0.031 mol of Ag2S.
Mass of Ag2S formed = Number of moles × Molar mass
=0.031mol×248gmol−1
=7.69g
Hence, the amount of Ag2S formed is 7.69 g.
So, option (a) is the correct answer.