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Question

If 4×96500C charge is passed through an electrolytic cell of dil. H2SO4 the total volume of gases evolved will be ____ (collected at STP).

A
89.6L
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B
44.8L
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C
67.2L
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D
11.2L
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Solution

The correct option is A 89.6L
Electrolysis of H2SO4 is given by following reaction
2H+1+2eH22H2OO2+2e1+4H+1
Above reaction states that 2 mole of electrons gives 1 mole of O2 and H2
Therefore, 4×96500C (4F) gives 4 mole of gas
Volume of 1 mole =22.4 L
Volume of 4 mole =22.4×4=89.6 L

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