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Question

If a groundwater contains H2S at a concentration of 2 mg/l, determine the pressure of H2S in head space of a closed tank containing the groundwater at 200C. Given that for H2S, Henry's constant is equal to 6.8×103 bar at 200C.

A
720 Pa
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B
77×102 Pa
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C
553 Pa
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D
55×102 Pa
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Solution

The correct option is A 720 Pa
Given
Conc. of Hydrogen sulphide in groundwater is 2mg/L
Henry's
constant for it is 6800bar
Solution
PH2S=Conc.H2S×Kh×18Molecularweight×106
Putting values
PH2S=710.5×105atm=719.5Pa=720Pa
The correct answer is A


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