If a is the fraction of N2O4⇌2NO2 molecules dissociated in the reaction (N2O4⇌2NO2), then at equilibrium, the total number of moles of N2O4 and NO2 present will be
N2O4⇌2NO2
Let x be the initial molecules present.
N2O4⇌2NO2
x − Total =x
x−a 2a Total =x+a
Excessx+a−x=a
Hence, the number of moles is a.