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Question

If at 298 K the bond energies of C - H, C - C, C - C and H - H bonds are respectively 414, 347, 615 and 435 kJ mol1, the value of enthalpy change for the reaction H2C = CH2(g) H3C CH3(g) at 298K will be


A

+250 kJ

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B

-250 kJ

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C

+125 kJ

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D

-125 Kj

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Solution

The correct option is D

-125 Kj


CH2 = CH2(g) + H2(g) H3C CH3(g)

414 × 4 = 1656 414 × 6 = 2484

615 × 1 = 615 347 × 1 = 347

435 × 1 = 435–– 347 × 1 = 347––

2706––– 2831–––

ΔH = 2706 2831 = 125 kJ


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