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Question

If at 298 K the bond energies of CH, CC, C=C and HH bonds are respectively 414,347,615 and 435 kJ mol^{-1}, the value of enthalpy change for the reaction:
H2C=CH2(g)+H2(g)H3CCH3(g) at 298K will be:

A
125 kJ
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B
+125 kJ
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C
250 kJ
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D
+250 kJ
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Solution

The correct option is A 125 kJ
H2C=CH2+H2H3CCH3
Bond break Energy Bond form Energy
HH 435KJmol1 2CH 2×(414)KJmol1
C=C 615KJmol1 CC 347KJmol1
Total enthalpy change is
435+6152×4141347
=125KJmol1 .

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