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Question

If Azimuthal quantum number l and k of elliptical orbit are related as l=k, what would be the maximum number of electrons in K,L,M and N shells?

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Solution

k of elliptical orbit corresponds to the length of the minor axis. Azimuthal quantum number l is equal to k . k cannot be equal to zero since the length of the minor axis would become zero in that case and the electron passes through the nucleus. Therefore l also cannot be zero, In that case, l=1,2,3,4 should correspond to s,p,d and f subshells. The number of orbitals in a subshell is given by 2l+1 which correspond to 3,5,7 and 9 orbitals are s,p,d,f subshells. Since each orbital contains 2 electrons, the subshells should possess 6,10,14 and 18 electrons respectively. K shell contains only 's ' subshell with 6 electrons. Similarly, L shell contains 16 electrons in s & p subshells, 'M ' shell contains 30 electrons in s,p & d subshells, 'N ' shell contains 48 electrons in s,p,d & f subshells.


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