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Thermodynamic Processes

If b1, b2, b3...

Question

If b1, b2, b3 are stepwise formation constants of MCl, MCl2, MCl3 and K is overall formation constant of MCl3, then in what ways can K be written?

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M C l

M C l_{2}

M C l_{3}

a, b

c

M C l_{3}

M C l, M {C l}_{2}, M {C l}_{3}

M C l > M {C l}_{2} > M {C l}_{3}

M + C l ⇋ M C l, K_{e q} = β_{1}

M C l + C l ⇋ M C l_{2}, K_{e q} = β_{2}

M C l + C l ⇋ M C l_{3}, K_{e q} = β_{3}

M + 3 C l ⇋ M C l_{3}, K_{e q} = K

K, β_{1}, β_{2}

β_{3}

H_{2} O

[F e (H_{2} O)_{6}]^{3 +}

[F e (H_{2} O)_{6}]^{3 +} + 3 e n \to [F e (e n)_{3}]^{3 +} + 6 H_{2} O

l o g K_{1} = 4.34

l o g K_{2} = 3.31

l o g K_{3} = 2.05

A \times 10^{B}

A + B

H_{2} O

[F e (H_{2} O)_{6}]^{3 +}

[F e (H_{2} O)_{6}]^{3 +} + 3 e n \to [F e (e n)_{3}]^{3 +} + 6 H_{2} O

log K_{1} = 4.34

log K_{2} = 3.31

log K_{3} = 2.05

A \times 10^{2 B}

B

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