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Question

If density of 2 molal sucrose solution is 1.4 gm/mL at 25 find osmotic pressure.

A
4.06 atm
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B
2 atm
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C
40.6 atm
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D
3.4 atm
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Solution

The correct option is B 40.6 atm
Given
Density=1.4 g/ml
Molecular weight=342
and m=2
Now,
Molarity M=1000×m×density1000×m×molecularweight
M=1000×2×1.41000×2×342
M=1.662
Now,
Osmotic pressure=iMRT
=1×1.662×0.082×298
=40.6 atm

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