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Question

If dichloromethane (DCM) and water (H2O) are used for differential extraction, which one of the following statements is correct ?

A
DCM and H2O would stay as lower and upper layer respectively in the S.F.
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B
DCM and H2O will be miscible clearly
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C
DCM and H2O would stay as upper and lower layer respectively in the separating funnel (S.F.)
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D
DCM and H2O will make trubid/colloidal mixture
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Solution

The correct option is A DCM and H2O would stay as lower and upper layer respectively in the S.F.
  • All Alkyl Halides are absolutely water insoluble.
  • All Alkyl Halides are dense as compared to water.
  • In a separating funnel upper layer is called layer-1 and the lower layer is called layer-2.
  • So the upper layer will be with less dense H2O and the lower layer will be denser DCM.
  • Hence option A is a correct answer.

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