If during an adiabatic process the pressure of mixture of gases is found to be proportional to square of its absolute temperature. The ratio of CP/CV for mixture of gases is
A
2
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B
1.5
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C
1.67
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D
2.1
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Solution
The correct option is A2 For an adiabatic process, the expression is PVγ=const As, PV=nRT ⟹P(nRTP)γ=const ⟹P1−γ⋅Tγ=const Given, P∝T−2 ⟹PT−2=const ⟹P⋅Tγ/1−γ=const ⟹γγ−1=+2 ⟹γ=−2(1−γ) ⟹γ=2