The correct option is D PV=23Ek
The pressure P can be expressed in terms of translational kinetic energy of the molecules, i.e.,
P=23E.
Here, E=12ρC2, which is the kinetic energy per unit volume.
⟹P=23×12×mnVC2.
⟹PV=23Ek, where Ek is the average kinetic energy per mole of a gas.