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Question

If EFe3+|Fe and EFe2+|Fe are 0.36V and 0.439V, respectively, then the value of EFe3+|Fe2+ is:

A
(360.439)V
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B
[3(0.36)+2(0.439)]V
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C
(0.360.0439)V
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D
[3(0.36)2(0.439)]V
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Solution

The correct option is B [3(0.36)+2(0.439)]V

Fe3++3eFe:ΔG1=3FEFe3++Fe

Fe2++2eFe:ΔG2=2FEFe2+|Fe

Fe3+eFe2+:ΔG3=FEFe2+|Fe

EFe3+|Fe2+=3EFe3+|Fe2EFe2+|Fe

[3(0.36)+2(0.439)]V


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