Fe3++3e−→Fe:ΔG1=−3FE⊖Fe3++Fe
Fe2++2e−→Fe:ΔG2=−2FE⊖Fe2+|Fe
Fe3+e−→Fe2+:→ΔG3=−FE⊖Fe2+|Fe
E⊖Fe3+|Fe2+=3E⊖Fe3+|Fe−2E⊖Fe2+|Fe
[3(−0.36)+2(−0.439)]V
Given standard E⊖:
Fe3++3e−→Fe; E⊖=−0.036V
Fe2++2e−→Fe; E⊖=−0.440V
The E⊖ of Fe3++e−→Fe2+ is: