If elements with principal quantum number n>4 were not allowed in nature, the number of possible elements would be
60
The maximum number of electrons in an orbit are 2n2. If n>4 , is not allowed, then the number of maximum electrons that can be in first four orbit are:
2(1)2+2(2)2+2(3)2+2(4)2=2+8+18+32=60
Therefore, possible elements can be 60.