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Question

If equal volumes of 0.1MKMnO4 and 0.1MK2Cr2O7 solutions are allowed to oxidise Fe2+toFe3+ in acidic medium, then Fe2+ oxidised will be :

A
more by KMnO4
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B
more by K2CrO7
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C
equal in both cases
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D
can't be determined
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Solution

The correct option is A more by K2CrO7
Cr changes from +6 to +3 oxidation state on reduction. But there are two Cr atoms per molecule, net change is 2×3=6.

Mn changes from +7 to +2 on reduction. So, change is 5.

Hence, for equal molar and volume solutions of K2CrO7 and KMnO4, more oxidation occurs from K2CrO7.

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