If excess water is added into a 100g bottle sample labelled as "112%H2SO4" and is reacted with 5.3gNa2CO3, then find the volume of CO2 evolved at STP after the completion of the reaction : [R=0.0821Latmmol−1K−1] H2SO4+Na2CO3→Na2SO4+H2O+CO2
A
2.46 L
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B
24.6 L
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C
1.12 L
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D
11.2 L
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Solution
The correct option is C 1.12 L Balanced chemical reaction : H2SO4+Na2CO3→Na2SO4+H2O+CO2
Moles = GivenmassMolarmass Moles of Na2CO3 = 5.3106=0.05mol Moles of H2SO4 = 11298=1.14mol For limiting reagent = MolesStochiometriccoefficent For Na2CO3 = 0.051=0.05 For H2SO4 = 11298=1.14. The ratio for Na2CO3 is less hence it is a limiting reagent. According to stoichiometric coefficient : Moles of CO2 formed = Moles of Na2CO3 reacted = 0.05 mol. Volume of CO2 evolved at STP conditions = 0.05×22.4=1.12L