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Question

If excess water is added into a 100g bottle sample labelled as 112% H2SO4 and is reacted with 5.3gNa2CO3, find the volume of CO2 evolved at 1 atm pressure and 300K temperature after the completion of the reaction:

H2SO4+Na2CO3Na2SO4+H2O+CO2

[R=0.0821Latmmol1K1]

A
2.46L
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B
24.6L
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C
1.23L
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D
12.3L
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Solution

The correct option is C 1.23L
1 mole of sodium carbonate produces 1 mole of carbon dioxide.

The number of moles of carbon dioxide produced from 5.3g of sodium carbonate is 5.3106=0.05 moles.

At 1 atm pressure and 300K temperature, 1 mole of carbon dioxide occupies a volume of 24.63L.

Volume of carbon dioxide produced from 5.3g of sodium carbonate is =0.05×24.63=1.23 L.

Hence, option C is correct.

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