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Question

If excess water is added into a bottle labelled as 109% H2SO4 and is reacted with 6.6 g Na2CO3 then find the volume of CO2 evolved at 1 atm and 273 K after the completion of the reaction.

A
22.4 L
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B
1.4 L
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C
2.2 L
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D
14.2 L
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Solution

The correct option is B 1.4 L
Na2CO3+H2SO4Na2SO4+H2O+CO2

Moles of Na2CO3=6.6 g106 g/mol0.0623 mol
According to the stoichiometry of the reaction,
1 mol Na2CO31 molCO2
Moles of CO2=0.0623 mol

From ideal gas equation,
V=nRTP
VCO2=0.0623 mol×0.0821 L atm K1 mol1×273 K1 atm
VCO21.4 L

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