The correct options are
A K would have been
d− block element and paramagnetic
B Cu would have been
s− block element
D Fe3+ ion would have 5 unpaired electrons
If Hund's rule isn't followed and energy of orbitals is governed by 'n' only and not
′n+l′ rule, then the order of energy of orbitals are in order.
1s 2s 2p 3s 3p 3d 4s 4p 4d 4f……… a) Electronic Configuration of
K is
19K=1s2 2s2 2p6 3s2 3p6 3d1 So,
K would be a
d− block element and paramagnetic due to an unpaired electron in d - orbital.
b)
29Cu=1s2 2s2 2p6 3s2 3p6 3d10 4s1 So,
Cu would have been
s− block element.
c)
24Cr=1s2 2s2 2p6 3s2 3p6 3d6 (or)
![](https://df0b18phdhzpx.cloudfront.net/ckeditor_assets/pictures/909519/original_7.png)
As there are 4 unpaired electron, then
Cr would be paramagnetic.
d) In
Fe3+, no. of electron = 23
Electronic configuration of
Fe3+ is
1s2 2s2 2p6 3s2 3p6 3d5 ![](https://df0b18phdhzpx.cloudfront.net/ckeditor_assets/pictures/909520/original_8.png)
So,
Fe3+ has 5 unpaired electrons.
∴ a, b, d are correct options.