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Question

If n1 and n2 are the boundary value principle quantum numbers of a portion of spectrum of emission spectrum of H atom, determine the wavelength (in metre) corresponding to last line (longest λ). Given :n1+n2=7,n2n1=3 and RH=1.097×107m1 (Give your answer in multiple of 106)

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Solution

Here
n2=5 & n1=2

So longest wavelength means least energy difference transition i.e. n2=5to n1=4

1λ=RH(1)2(142152)

so λ=4×106m

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