If N is the number of spheres in the unit cell, then total no. of tetrahedral voids is
N
2N
N/2
4N
We know that the no. of tetrahedral voids is twice the number of particles in a given unit cell.
In which of the following structures coordination number for cations and anions in the packed structure will be same ?
(a) Cl− ions form fcc lattice and Na+ ions occupy all octahedral voids of the unit cell
(b) Ca2+ ions form fcc lattice and F− ions occupy all the eight tetrahedral voids of the unit cell
(c) O2− ions form fcc lattice and Na+ ions occupy all the eight tetrahedral voids of
(d) S2− ions form fcc lattice and Zn2+ ions go into alternate tetrahedral voids of the unit cell
If N is the number of spheres in the unit cell, then total no. of octahedral voids is the cell is