The correct option is D NP > Ne or NP < Ne depending on the nature of impurity
When a pure semiconductor is doped with a trivalent impurity, we get a P−type semiconductor in which, NP>Ne
Similarly, When a pure semiconductor is doped with a pentavalent impurity, we get a N−type semiconductor in which, Ne>NP.
So, whether NP>Ne or Ne>NP, it depends upon the nature of the impurity.
Hence, (D) is the correct answer.