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Question

If NaCl is doped with 10−3 mol % of SrCl2, what is the concentration of cation vacancies?

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Solution

It is given that NaCl is doped with 10−3 mol% of SrCl2.

This means that 100 mol of NaCl is doped with 10−3 mol of SrCl2.

Therefore, 1 mol of NaCl is doped withmol of SrCl2

= 10−5 mol of SrCl2

Cation vacancies produced by one Sr2+ ion = 1

Hence, the concentration of cation vacancies created by SrCl2 is 6.022 × 108 per mol of NaCl.


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