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Question

If NaCl is doped with 103 mol per cent of SrCl2, what is the concentration of cation vacancy?

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Solution

Na+ClNa+Cl
ClClNa+
Sr2+ClNa+Cl
ClNa+ClNa+
Number of cationic vacancies =103×6.023×1023100=6.023×1018 vacancies per mol

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