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Question

If Nacl is doped with 10^ -3 mol % srcl2 ,what is the concentration of cation vacancies?

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Solution

Answer: 6.02 x 1018 mol-1

The Solution given is as follows:

On doping NaCl by SrCl2, one Sr2+ ion replaces two Na+ ion.

So, no. of moles of cation vacancy in 100ml NaCl = 10-3

no of moles of cation vacancy in 1 mole NaCl = 10-3/100 = 10-5

Thus, total cation vacancy
= 10-5 x NA
= 10-5x 6.022 x 1023
= 6.022 x 1018

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