Let →OA=→a and →OB=→b be two non zero and non-collinear vectors.
Let →OP=→r be any vector coplanar with →a and →b. Through P, draw PM and PN parallel to →a and →b respectively. Then, from △OMP,
→PO=→OM+→MP [by triangle law of vector addition]
⇒→r=t1→a+t2→b, where t1 and t2 are suitable scalars.
If →a∥→b, then →a=m→b [where m is a suitable scalar].