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Question

If resistivity of pure silicon is 3000Ωm and the electron and hole mobilities are 0.12m2v-1s-1 and 0.045m2v-1s-1 respectively. Determine the resistivity of a specimen of the material when 1019 atoms of phosphorous are added per m3 Given e= 1.6×10-19C, p=3000Ω, μe=0.12m2v-1s-1, μh=0.045m2v-1s-1.


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Solution

Step 1. Given data:

Resistivity of Silicon ρ = 3000Ωm

Electron mobility μe = 0.12m2v-1s-1

Hole mobility μh = 0.045m2v-1s-1

No. of phosphorous atoms = 1019m-3

Charge on electrons e = 1.6×10-19C

Step 2. Calculations:

The resistivity of silicon (Si) metal is given by,

ρ=1σ=1eneμe+nhμh

Where ne=number of electrons.

nh=number of holes

For pure Silicon, as given in the question,

ne=nh=ni

So the formula for resistivity becomes,

ρ=1eniμe+μh

Or ni=1eρμi+μh, Putting all the given values, we get

n subscript i equals fraction numerator 1 over denominator 1.6 cross times 10 to the power of negative 19 end exponent cross times 3000 cross times open parentheses 0.12 plus 0.045 close parentheses end fraction
n subscript i equals space 1.26 cross times 10 to the power of 16 m to the power of negative 3 to the power of blank end exponent

When 1019atoms of phosphorous are added per m3, the semiconductor becomes n-type semiconductor.

Or it becomes pentavalent as the atoms of phosphorus completely occupy the holes as 1019>1.26×1016

Hence, in that case, we will find the resistivity of ne=1019

Resistivity ρ = 1neμee=11.6×10-19×1019×0.12=5.21Ωm

Hence, the resistivity of a specimen is 5.21Ωm.


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