If the activation energy of a reaction is 480.9kJmol−1, calculate the fraction of molecules at 400oC which have enough energy to react to form the products.
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Solution
Fraction of molecules which have enough energy to react to form the products is given by
Fraction= e−EA/RT(1)
Given, EA= 480.9KJ/mol
R=8.314J/mol
T=400°C=(273+400)K+673K
Putting the value in (1) we get,
Fraction of molecule required =e−480.9×1038.314×673=e−85.95=4.75×10−38