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Question

If the Aufbau principle had not been followed, Ca(Z=20) would have been placed in the?

A
s-block
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B
p-block
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C
d-block
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D
f-block
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Solution

The correct option is C d-block
Electronic configuration of Ca is 1s22s22p63s23p64s2.
Filling of 3d orbital starts after the filling of 4s orbitals. If the Aufbau principle had not been followed, the filling of 3d orbital would have been prior to filling of 4s orbital and the electronic configuration of Ca would have been 1s22s22p63s23p63d2 and it would have been placed in the d-block. Hence, correct answer is C.

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