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Question

If the azimuthal quantum number could have the value of n also then:

A
Sc(Z=21) would have configuration as 1s21p62s22p62d33s2
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B
Fe(Z=26) would have two unpaired electrons
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C
Fe2+ and Fe3+ would be paramagnetic and coloured
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D
Cu+ would be coloured and paramagnetic
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Solution

The correct options are
A Sc(Z=21) would have configuration as 1s21p62s22p62d33s2
B Fe(Z=26) would have two unpaired electrons
C Fe2+ and Fe3+ would be paramagnetic and coloured
If n=n then l=0,1,2,3,n

Energy order, 1s<1p<2s<2p<3s<2d

a)(Z=21), 1s21p62s22p63s22d3 :Correct

b)(Fe=26), 1s21p62s22p63s22d8


Two unpaired electrons : correct

c)Fe2+=1s21p62s22p62d8
(Valence shell 3s electrons are taken out)
Fe3+=1s21p62s22p62d7
Both have unpaired electrons in the d orbital
Thus, coloured: Correct

d) Cu=1s21p62s22p63s22d103p1
Cu+=1s21p62s22p63s22d10
Colourless: Incorrect

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