If the binding energy of the electron in a hydrogen atom is 13.6 eV, the energy required to remove the electron from the first excited state of Li++ is
A
122.4 eV
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B
30.6 eV
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C
13.6 eV
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D
3.4 eV
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Solution
The correct option is B30.6 eV Using En=−13.6×Z2n2eV For first excited state n = 2 and for Li++, Z = 3 ∴E=−13.622×32=−13.6×94=−30.6eV.