The correct options are
A The two
F atoms are at
180∘ with respect to each other
B Maximum 4 atoms are present in the same plane
C P−Cl bond is longer than
P−F bond
D The
d− orbital of 'P' involved in the formation of
PF2Cl3 is
dz2Hybridisation of
PCl3F2 is
sp3d so the structure would be trigonal bipyramidal. The zero dipole moment suggests the structure as follow:
A) According to Bent's rule the most electronegative elements occupy the axial positions in the trigonal bipyramidal geometry. Hence two F atoms are at
180∘ with respect to each other.
B) There are a maximum of 4 atoms in the same plane. There are
P and 3 equatorial
Cl atoms.
C) As size of
Cl is greater than the size of
F,
P−Cl bond is longer than
P−F bond.
D) In
sp3d hybridisation, the
d-orbital involved here is
dz2, since it is the lowest energy
d-orbital.