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Question

If the distance between Na+ and Cl− ions in sodium chloride crystal is ypm, the length of the edge of the unit cell is:

A
4y pm
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B
y4 pm
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C
y2 pm
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D
2y pm
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Solution

The correct option is C 2y pm
NaCl is a face centred cubic lattice in which Na+ is placed in octahedral voids which are present along the edges of the FCC lattice. Therefore length of unit cell will be twice the distance between Na+ and Cl ions.

Given, (r++r)=y pm

a=2(r++r)=2y pm

Option D is correct.

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