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Question

If the edge length of a KCl unit cell is 488 pm, what is the length of KCl bond if it crystallises in the fcc structure?

A
122 pm
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B
244 pm
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C
488 pm
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D
974 pm
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Solution

The correct option is D 244 pm
As KCl has rock salt like structure in which anions are present at corners and cations are present at edge centre.

So, edge length a=2× bond length of KCl

488pm=2× bond length of KCl

Therefore, bond length of KCl=4882 pm =244 pm

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