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Question

If the gas 'X' behaves ideally, then the pressure P of gas at 27oC is :

A
12.32 atm
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B
24.63 atm
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C
1 atm
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D
6.15 atm
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Solution

The correct option is B 24.63 atm
Given,
Cp=0.125 cal/g,Cv=0.075 cal/g
Also as we know,
CpCv=RM
M=20.1250.075=40
Also, CpCv=0.1250.075=53=1.66, so gas is monoatomic, also molar mass of gas is 40 so gas is Ar.
and according to ideal gas equation

PV=nRT(n=wM=20040=5)
P×5=20040×0.0821×300
P=24.63 atm.

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