If the ideal gas is diatomic and its increase in internal energy is 100J then the work performed by gas is : (Ignore vibrational degree of freedom)
A
80J
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B
180J
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C
100J
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D
20J
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Solution
The correct option is A80J U=α√VHereU=Kineticenergyofidealgas (55)b5 U=nCVT ⇒nCVT=α√V....(i)T=PVnR......(ii) sub. (2) in (1) (CVR).PV=α√V ⇒P=(α.RCV)1√V w=−∫PdV=−(αRCV)∫dV√V =−[(α)(γ−1).1(1/2)(√V)]V2V1 w=−2(α)(γ−1)(√V2−√V1) Work done by the gas = −w=2(α) (γ−1)(√V2−√V1) For diatomic gas with no vibrational degree of freedom CV=32R+2×12R CV=5/2R ΔU=α(√V2−V1)=100J W=2(α)(γ−1)(√V2−V1)=(2)(γ−1)×100 ∵γ=CPCV=75 (γ−1)=(75−1)=(25) W=(2)(25)(100)J=80J