Consider the word EAMCET. Arranging the letters in alphabetical order results in
ACEEMT. This will be the first word in the dictionary. Thus keeping A fixed, the rest of the letters can be re-arranged in 5!2! or 60 ways.
Now let the first Letter be C, the rest of the letters can be re-arranged in 5!2! or 60 ways.
Now let the first letter be E, therefore the first word in the dictionary which starts with E will be EACEMT. Let the third letter be C, the rest three letters can be re-arranged in 3! or 6 ways. Similarly for E being the third letter, 6 ways. Now let M be the third letter, thus the first word will be EAMCET.
Hence rank of the word EAMCET will be 60+60+6+6+1=120+12+1=133