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Question

If the masses of Cr and O are in the ratio 13:12 in CrO3, then the ratio of O that combines with the same mass of Cr in Cr2O3 and Cr2O3 is:

A
1:2
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B
1:4
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C
3:7
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D
2:5
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Solution

The correct option is C 3:7
First we will use a mass of oxygen of 12 g.

The reaction of oxygen and Chromium to from dichromate CrO7 is
2Cr+7O2 2CrO7
Mole ratio is 2:7:2
In this case 13 g of Cr will be used in this equation.
Calculating the moles of Cr (molar mass = 52)
moles = mass/molar mass
= 13/52
= 0.25 moles
mole ratio between Cr:O7 is 2:7
Therefore the moles of oxygen is 0.875, calculate the mass using this mole value.
mass = moles × molar mass
= 0.875 × 28 = 28 g
The ratio of the oxygen in the 2 equations then is:
12 g: 28 g
the ratio, therefore, is 3:7

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