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Question

If the number of protons in an atom is equal to the number of electrons, then why is it necessary to say that the atomic number of an atom is equal to the number of electrons, not protons ?

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Solution

It is not necessary to say so.
You can define atomic number by any way in case of atoms as no. of protons is equal to the no. of electrons.
While in case of ions, it is necessary to define the atomic number as the number of protons only. This is because, in a particular ion of any atom, the number of protons remains the same but the number of electrons changes.

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