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Question

If the potential energy between two molecules is given by U=Ar6+Br12, then at equilibrium, separation between molecules and the potential energy respectively are:

A
(B2A)16,(A22B)
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B
(BA)16,0
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C
(2BA)16,(A24B)
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D
(2BA)16,(A22B)
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Solution

The correct option is C (2BA)16,(A24B)
Given : U=Ar6+Br12
For equilibrium,
F=dUdr=0
(A(6r7))+B(12r13)=0
0=6Ar712Br136A12B=1r6
Separation between molecules, r=(2BA)1/6

Also, Potential energy,
U at (r=(2BA)1/6)=A2B/A+B4B2/A2
=A22B+A24B=(A24B)

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