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Question

If the radius of an atom of an element which forms a body centered cubic unit cell is 173.2 pm , the volume of unit cell in cm3 is:

A
3.12×1023
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B
6.4×1023
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C
3.2×1024
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D
2.13×1023
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Solution

The correct option is B 6.4×1023
Body centred cubic unit cell:
Atoms present at each corner and at the body centre of the unit cell.
diagonal of cube:
d2=a2+a2+a2=3a2
(4r)2=3a2
a=4r3 (i)
Volume of cube =a3
V=6.4×1023cm3

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