If the ratio of specific heat of a gas at constant pressure to that at constant volume is γ, the change in internal energy of the mass of gas, when the volume changes from Vto2V at constant pressure P, is
A
Rγ−1
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B
PV
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C
PVγ−1
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D
γPVγ−1
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Solution
The correct option is DPVγ−1 At constant pressure, change in internal energyΔU=nCvΔT Now,CpCv=γ ⇒1+RCv=γ ⇒Cv=Rγ−1 Using Charle's law, final temperature=2\times initial temperatue=2T Thus, ΔU=nCv(2T−T)=nCvT=nRTγ−1=PVγ−1