If the ratio of specific heat of a gas at constant pressure to that at constant volume is γ , the change in internal energy of the mass of gas, when the volume changes from V to 2V at constant pressure P is :
A
R(γ−1)
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B
PV
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C
PV(γ−1)
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D
γPV(γ−1)
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Solution
The correct option is CPV(γ−1) Using first law we have ΔQ=ΔU+ΔW For an isobaric process we have ΔW=PV And ΔQ is given as nCpΔT=nγRγ−1ΔT Using Gas Law equation, we have PV=nRΔT Thus, we get ΔQ=γγ−1PV Hence, ΔU=γγ−1PV−PV=PVγ−1