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Question

If the solubility of lithium sodium hexafluoroaluminate, Li3Na3(AlF6)2 is 's' mol L1, its solubility product is equal to -


A

s8

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B

12s3

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C

18s3

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D

2916s8

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Solution

The correct option is D

2916s8


Li3Na3(AlF6)2(s) 3Li+ + 3Na+ + 2AlF66

Let solubility of salt is 's' mol L1

So [Li+] = 3s = [Na+]

[AlF66] = 2s

So Ksp = [Li+]3[Na+]3[AlF66]2

= (3s)3(3s)3(2s)

= 2916 s8


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