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Question

If the solubility of PbBr2 is 'S' moles per litre, considering 100% ionisation, its solubility product is:

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Solution

PbBr2 Pb+2+2Br
At t=0 : S O O
At equilibrium: O S 2S
Therefore , Solubility product (Ksp)=[Pb2+][Br]2
=(s)(2s)2
=(s)(4s2)
=4s3
Therefore, solubility product is 4s3 moles per litre.

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